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With the relay energised (IGN & Start closed), the top relay arm swings down to the 24V starter motor and the bottom arm reconnects the "upper" battery's -ve to +12V, hence making the upper battery's +ve terminal (12 + 12 =) 24V.
At no time does the lower 12V part see 24V, it only ever sees the lower battery's 12V.
If however the lower arm connects to +12V BEFORE the upper contact has broken it's upper contact, you then have a short across the upper 12V battery.
That's the failsafe part - if using TWO SPDT relays (or several SPST) instead of a DPDT relay, you must ensure the upper arm breaks from the upper contact before the lower arm makes its lower contact.
Of course all you have to do is pair up 2 batteries in parallel for your Main and Aux/secondary batteries respectively and connect according to that diagram.
However I am so conditioned into NOT having paralleled batteries (except when being used or when being charged) that I automatically think of (automatic) battery isolation and that's what I mention in the diagram's notes.
But that fig was for ONE extra battery added to the Main battery for a 24V starter.
I'd assume your 4 batteries are separate to your main battery, hence for isolation four isolating relays are required else 4 terminals need to be disconnected (IMO after a few or several hours if leaving unused or not charging).